Bentel Research Group
 

[as First author or corresponding]

Synthesis of Petitjeanite Bi3O(OH)(PO4) Photocatalytic Microparticles: Effect of Synthetic Conditions on Crystal Structure and Activity Towards Degradation of Aqueous Perfluorooctanoic Acid (PFOA).
ACS Appl. Mater. Interfaces. 2023, 15, 17, 20854–20864.
DOI: 10.1021/acsami.2c20483

 
 

Near-Quantitative Defluorination of Perfluorinated and Fluorotelomer Carboxylates and Sulfonates with Integrated Oxidation and Reduction.
Environ. Sci. Technol. 2021, 55, 10, 7052-7062.
DOI: 10.1021/acs.est.1c00353

 
es1c00353_0010.jpeg
 

Enhanced Degradation of Perfluorocarboxylic Acids (PFCAs) by UV/Sulfite Treatment: Reaction Mechanisms and System Efficiencies at pH 12.
Environ. Sci. Technol. Lett. 2020, 7, 5, 351–357.
DOI: 10.1021/acs.estlett.0c00236

 
pH paper TOC.gif
 

Degradation of Perfluoroalkyl Ether Carboxylic Acids (PFECAs) with Hydrated Electrons: Structure-Reactivity Relationships and Environmental Implication.^^
Environ. Sci. Technol. 2020, 54, 4, 2489–2499. ^^ACS Editors’ Choice
DOI: 10.1021/acs.est.9b05869 (open access)

 
PFECA paper.jpeg
 

Defluorination of Per- and Polyfluoroalkyl Substances (PFAS) with Hydrated Electrons: Structural Dependence and Implications to PFAS Remediation and Management.
Environ. Sci. Technol. 2019, 53, 7, 3718–3728.
DOI: 10.1021/acs.est.8b06648 (open access).

 
PFAS paper.jpeg
 
 

[as co-author]

Advancing PFAS characterization: Development and optimization of a UV-H2O2-TOP assay for improved PFCA chain length preservation and organic matter tolerance.
Sci. Total Environ. 2024, 946, 10, 174079
DOI: 10.1016/j.scitotenv.2024.174079

 
 
 

Oxidative Transformation of Nafion-Related Fluorinated Ether Sulfonates: Comparison with Legacy PFAS Structures and Opportunities of Acidic Persulfate Digestion for PFAS Precursor Analysis.
Environ. Sci. Technol. 2024, 58, 6415-6424
DOI: 10.1021/acs.est.3c06289

 
 

Hexagonal prism-like Fe1−xS@SC nanorod derived from MIL-88A (Fe) as peroxydisulfate activator for tetracycline degradation: Performance and mechanism.
Sep. Purif. Technol. 2024, 335, 125962.
DOI: 10.1016/j.seppur.2023.125962

 
 

Integrated Data-Driven Framework to Prevent Chemical Water Pollution.
One Earth. 2023, 6, 8, 952-963.
DOI: 10.1016/j/oneear.2023.07.001

 
 

Semiconductor-hydrophobic material interfaces as a new active site paradigm for photocatalytic degradation of perfluorocarboxylic acids.
J. Hazard. Mater. 2023, 453, 131437.
DOI: 10.1016/j.jhazmat.2023.131437

 
 

Nitrogen-Doped Graphdiyne Nanotubes for Metal-Free Activation of Peroxymonosulfate and Enhanced Degradation of Recalcitrant Heterocyclic Contaminants.
ACS EST Engg. 2023, 3, 7, 969-980.
DOI: 10.1021/acsestengg.3c00009

 
 

Defluorination of Omega-Hydroperfluorocarboxylates (ω-HPFCAs): Distinct Reactivities from Perfluoro and Fluorotelomeric Carboxylates.
Environ. Sci. Technol. 2021, 55, 20, 14146-14155.
DOI: 10.1021/acs.est.1c04429

 
 
 

Presentations

 

Underline = presenter

Bentel, M.J.; Mason, M.M.; Cates, E.L. “Synthesis of Petitjeanite Bi3O(OH)(PO4)2 Photocatalytic Microparticles: Effect of Synthetic Conditions on Crystal Structure and Activity Towards Degradation of Aqueous Perfluorooctanoic Acid (PFOA).” Presented at the 266th American Chemical Society National Meeting, San Francisco, CA, USA, August 13-17, 2023.

Bentel, M.J.; Sui, W.; Liu, Z.; Maza, W.; Ren, C.; Liu, J. “Novel degradation mechanism for rapid photochemical PFAS defluorination”. Presented at the 265th American Chemical Society National Meeting, Indianapolis, IN, USA, March 26-30, 2023

Bentel, M.J. “Navigating the Complexities of PFAS Analysis: Techniques, Challenges, and Best Practices” Invited talk at the National Institute Occupational Safety & Health (NIOSH), Cincinnati, OH, March 23, 2023

Bentel, M.J.; Liu, J. “Addressing Forever Chemicals: Chemical Destruction of Aqueous Per- and Polyfluoroalkyl Substances (PFAS)” Chemical & Environmental Engineering Department, University of Cincinnati, September 30, 2022

Mason, M.M.; Bentel, M.J.; Cates, E.L. “Role of Oxygen Vacancies (VO) in Photocatalytic stability and activity of PFAS-active Bi3O(OH)(PO4)2 Microparticles” Presented at the 264th American Chemical Society National Meeting, Chicago, IL, USA, August 21-25, 2022

Bouteh, E.; Bentel, M.J.; Cates, E.L. “Revised mechanism for explaining PFOA degradation enhancement by the use of graphitic carbon with semiconductor photocatalytic materials” Presented at the 264th American Chemical Society National Meeting, Chicago, IL, USA, August 21-25, 2022

Bentel, M.J. “Chemical Destruction of Aqueous Per- and Polyfluoroalkyl Substances (PFAS): Are PFAS Truly ‘Forever Chemicals’?”. Invited talk at the Civil & Environmental Engineering Department, Carnegie Mellon University, October 22, 2021

Bentel, M.J. “Chemical Destruction of Aqueous Per- and Polyfluoroalkyl Substances (PFAS): Are PFAS Truly ‘Forever Chemicals’?”. Invited talk at Environmental Engineering & Earth Sciences Department, Clemson University, October 8, 2021

Bentel, M.J. “Chemical Destruction of Aqueous Per- and Polyfluoroalkyl Substances (PFAS): Are PFAS Truly ‘Forever Chemicals’?”. Invited talk at WESTalks seminar series, University of British Columbia, Canada, October 7, 2021

Sui, W., Bentel, M.J., Liu, J. Structural-reactivity relationship for reductive defluorination of per- and polyfluoroalkyl substances (PFASs) with hydrated electrons. Presented at the 2019 Southern California Conferences for Undergraduate Research, San Marcos, CA, November, 2019.

Bentel, M.J.; Yu, Y.; Xu, L.; Li, Z.; Wong, B.M.; Men, Y.; Liu, J. “Defluorination of per- and polyfluoroalkyl substances (PFASs) with hydrated electrons: Structural dependence and implications to PFAS remediation and management”. Presented at the 258th American Chemical Society National Meeting, San Diego, CA, USA, August 25-29, 2019.

Bentel, M.J.; Liu, Z.; Yu, Y.; Men, Y.; Liu, J. “Enhancing photochemical defluorination of per- and polyfluoroalkyl substances (PFASs)”. Presented at the 258th American Chemical Society National Meeting, San Diego, CA, USA, August 25-29, 2019.

Bentel, M.J.; Harake, M.; Wang, L.; Lin, S.; Sun, M.; Liu, J. “Chemical degradation of environmentally persistent fluorochemicals in aqueous film-forming foam (AFFF)”. Presented at the 258th American Chemical Society National Meeting, San Diego, CA, USA, August 25-29, 2019.

Harake, M., Bentel, M.J., Sun, M., Lin, S., Liu, J. “High-performance treatment of PFASs from investigation-derived waste: Integrating advanced oxidation-reduction and membrane concentration”. Poster at SERDP & ESTCP Meetings on PFAS Treatment, San Diego, August, 2019.

Bentel, M.J., Yu, Y., Xu, L., Kwon, H., Wong, B.M., Men, Y., Liu, J. “Degradation of Perfluoroalkyl Ether Carboxylic Acids (PFECAs) with Hydrated Electrons: Structure-Reactivity Relationship and Environmental Implications”. Poster at SERDP & ESTCP Meetings on PFAS Treatment, San Diego, August, 2019.

Bentel, M.J.; Yu, Y.; Xu, L.; Li, Z.; Wong, B.M.; Men, Y.; Liu, J. “Understanding the structure-activity relationship of emerging perfluoroether acids (PFEAs) by UV-generated hydrated electron”. Presented at the 257th American Chemical Society National Meeting, Orlando, FL, USA, March 31-April 4, 2019.

Bentel, M.J.; Yu, Y.; Xu, L.; Wong, B.M.; Men, Y.; Liu, J. “Carbon-fluorine bond cleavage: Experimental and computational investigation into the mechanism and reactivity of reductive cleavage of carbon-fluorine bonds via a hydrated electron probe in aqueous environments”. Presented at the American Chemical Society, Division of Fluorine Chemistry, 24th Winter Fluorine Conference, Clearwater Beach, FL, USA, January 13-18, 2019.

Bentel, M.J.; Liu, J. “Development of a Complete Treatment Technology for Aqueous Per- and Polyfluoroalkyl Substances”. Invited talk at Environmental Sciences Department, University of California, Riverside, December 5, 2019.

Bentel, M.J.; Yu, Y.; Xu, L.; Li, Z.; Wong, B.M.; Men, Y.; Liu, J. “Defluorination of per- and polyfluoroalkyl substances (PFASs) with hydrated electrons: Structural dependence and implications to PFAS remediation and management”. Poster at SERDP & ESTCP Symposium 2018 Washington, D.C., USA, November 27-29, 2018.

Bentel, M.J.; Harake, M; Sun, M.; Lin, S.; Liu, J. “Sequential Treatment of Aqueous Film Forming Foam (AFFF)-Containing Solutions with Membrane Concentration and Chemical Degradation”. Poster at SERDP & ESTCP Symposium 2018, Washington, D.C., USA, November 27-29, 2018.

Harake, M., Bentel, M.J., Liu, J. Treatment of AFFF contaminated water using hydrated electron. Presented at the 2018 Southern California Conferences for Undergraduate Research, Pasadena, CA, November, 2018.

Bentel, M.J., Yu. Y., Xu, L., Wong, B.M., Men, Y., Liu, J. Defluorination of PFASs with hydrated electrons: Structural dependence and implications to remediation and management. Poster at Gordon Research Conference on Environmental Sciences: Water. Holderness, NH, June, 2018

Bentel, M.J.; Yu, Y.; Xu, L.; Li, Z.; Wong, B.M.; Men, Y.; Liu, J. “Probing defluorination mechanisms for perfluorocarboxylic acids by a UV-mediated reduction system”. Presented at the 255th American Chemical Society National Meeting, New Orleans, LA, USA, March 18-22, 2018.

 

 media

 

WESTalks Global Water Seminar Series, University of British Columbia
8 October 2021 [Zoom]

 
 
 

American Chemical Society (ACS) Committee on Environmental Improvement (CEI) Film Award - 2nd place (2019)